catena-Poly[[(pyridine-κN)copper(II)]-μ3-pyridine-2,6-dicarboxylato-κ3O2:O2′,N,O6:O6′]
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چکیده
منابع مشابه
catena-Poly[[(pyridine-κN)copper(II)]-μ3-pyridine-2,6-dicarboxylato-κ3 O 2:O 2′,N,O 6:O 6′]
In the title compound, [Cu(C(7)H(3)NO(4))(C(5)H(5)N)](n), the Cu(II) atom is in a slightly distorted octa-hedral coordination environment. Each Cu(II) atom is bound to two N atoms and one O atom of the pyridine-dicarboxyl-ate (PDA) ligand in a tridentate manner, one N atom of the pyridine mol-ecule and two bridging carboxyl-ate O atoms of adjacent PDA ligands, leading to a linear one-dimensiona...
متن کاملcatena-Poly[[di-μ-aqua-bis[aquacobalt(II)]]-bis(μ3-1H-benzimidazole-5,6-dicarboxylato]
The title compound, [Co(2)(C(9)H(4)N(2)O(4))(2)(H(2)O)(4)](n), is a one-dimensional polymeric complex with bridging 1H-benzimidazole-5,6-dicarboxyl-ate and aqua ligands. The Co(II) cation has an octa-hedral coordination environment provided by an NO(5) donor set. Adjacent polymeric chains extended along the [100] direction are linked by O-H⋯O and N-H⋯O hydrogen bonds, generating a three-dimensi...
متن کاملcatena-Poly[μ2-iodido-diiodidobis(μ3-pyridine-2-thione-κ3 S:S:S)(μ2-pyridine-2-thione-κ2 S:S)tricopper(I)]
In the title compound, [Cu(3)I(3)(C(5)H(5)NS)(3)](n), a polymeric structure is formed along [100] through bridging iodide and pyridine-2-thione ligands. The metal atoms are engaged in [Cu(3)S(3)] and [Cu(2)S(2)] rings sharing Cu-S edges, with the [Cu(2)S(2)] rings located about inversion centers. Cu(I) atoms bridged by iodide ions exhibit the shortest Cu⋯Cu separation in the polymer [2.8590 (14...
متن کاملcatena-Poly[[aquanickel(II)]-μ-pyridine-2,6-dicarboxylato-[aquanickel(II)]-μ-2,5-di-4-pyridyl-1,3,4-thiadiazole]
The two independent Ni(II) ions in the one-dimensional title complex, [Ni(2)(C(7)H(3)NO(4))(2)(C(12)H(8)N(4)S)(H(2)O)(2)](n) or [Ni(2)(pydc)(2)(bpt)(H(2)O)(2)](n) (H(2)pydc = pyridine-2,6-dicarboxylic acid and bpt = 2,5-di-4-pyrid-yl-1,3,4-thia-diazole), have different coordination environments. One Ni(II) ion is in a slightly-distorted octa-hedral coordination environment formed by three O ato...
متن کاملcatena-Poly[[aquadioxidouranium(VI)]-μ3-4,4′-oxydibenzoato]
The title compound, [UO(2)(C(14)H(8)O(5))(H(2)O)](n), is a polymeric UO(2) complex bridged by 4,4'-oxydibenzoate ligands. One carboxyl-ate group of the bridging ligand chelates a uranyl cation while the other carboxyl-ate group of the ligand bridges two other two uranyl cations, forming a double-chain polymeric structure. The central U(VI) atom is seven-coordin-ated in a distorted UO(7) penta-g...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2009
ISSN: 1600-5368
DOI: 10.1107/s1600536809005212